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Chemodex
1,1-Bis(phenylsulfonyl)ethylene
75
CHF
CHF 75.00
In stock
CDX-B0127-G0011 gCHF 75.00
CDX-B0127-G0055 gCHF 326.00
Product Details | |
---|---|
Synonyms | 1,1-Bis(benzenesulfonyl)ethylene |
Product Type | Chemical |
Properties | |
Formula | C14H12O4S2 |
MW | 308.4 |
CAS | 39082-53-6 |
Source/Host Chemicals | Synthetic. |
Purity Chemicals | ≥98% (HPLC) |
Appearance | White to faint yellow powder. |
Solubility | Soluble in toluene. |
Identity | Determined by NMR. |
Declaration | Manufactured by Chemodex. |
Other Product Data |
Click here for Original Manufacturer Product Datasheet |
InChi Key | KABQEPJVQFXVIN-UHFFFAOYSA-N |
Smiles | C=C(S(=O)(=O)C1=CC=CC=C1)S(=O)(=O)C1=CC=CC=C1 |
Shipping and Handling | |
Shipping | AMBIENT |
Short Term Storage | +4°C |
Long Term Storage | -20°C |
Handling Advice |
Keep cool and dry. Protect from light and moisture. |
Use/Stability | Stable for at least 2 years after receipt when stored at -20°C. |
Documents | |
MSDS | Download PDF |
Product Specification Sheet | |
Datasheet | Download PDF |
Description
Synthetic compound equivalent to the ethylene 1,2-dipole. Dienophile used for Diels-Alder reactions and useful synthon for neutral homologation of ketones. Used in the preparation of α,α-disubstituted alpha-amino acid derivatives.
Product References
(1) O. De Lucchi, et al.; Tetrahedron Lett. 25, 3643, (1984) | (2) O. De Lucchi, et al.; Tetrahedron Lett. 25, 3647, (1984) | (3) O. De Lucchi, et al.; Zeitschr.f. Kristallogr. 170, 267 (1985) | (4) A.N. Alba, et al.; Chemistry 16, 5354 (2010) | (5) R.L. Atienza & K.A. Scheidt; Aust. J. Chem. 64, 1158 (2011)