Di-(2-picolyl)amine

CHF 51.00
In stock
CDX-B0134-GG252.5 gCHF 51.00
CDX-B0134-G0055 gCHF 89.00
CDX-B0134-G02525 gCHF 357.00
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Product Details
Synonyms Dipicolylamine; DPA; Bis(2-pyridylmethyl)amine; 2,2'-Bis(pyridylmethyl)amine; NSC 176070
Product Type Chemical
Properties
Formula

C12H13N3

MW 199.25
CAS 1539-42-0
Source/Host Chemicals Synthetic
Purity Chemicals ≥95% (GC)
Appearance Yellow to orange liquid.
Solubility Sligthly soluble in water.
Identity Determined by NMR.
Declaration Manufactured by Chemodex.
Other Product Data

Click here for Original Manufacturer Product Datasheet
Our product description may differ slightly from the original manufacturers product datasheet.

InChi Key KXZQYLBVMZGIKC-UHFFFAOYSA-N
Smiles C(NCC1=CC=CC=N1)C1=CC=CC=N1
Shipping and Handling
Shipping AMBIENT
Short Term Storage +4°C
Long Term Storage -20°C
Handling Advice Keep cool and dry.
Protect from light and moisture.
Use/Stability Stable for at least 2 years after receipt when stored at -20°C.
Documents
MSDS Download PDF
Product Specification Sheet
Datasheet Download PDF

Building block for synthesis. DPA is a secondary amine with two picolyl substituents. The compound is a tridentate ligand in coordination chemistry and commonly used to produce Zn-based chemosensors/probes, such as Zinpry. As a tridentate ligand this compound provides three nitrogen donors that affords good selectivity for Zn2+ over biologically relevant metals such as Na+, K+, Mg2+ and Ca2+, and leaves coordination sites free for anion binding. The amino nitrogen of the DPA group is a good candidate as an electron donor in either photoinduced electron transfer or photoinduced charge transfer (PET or PCT) sensors. Zn(II)–DPA complexes are widely used in anion recognition and sensing.

Product References

(1) E.M. Nolan & S.J. Lippard; Inorg. Chem. 43, 8310 (2004) | (2) N.C. Lim & C. Bruckner; Chem. Commun. 2004, 1094 (2004) | (3) H.-W. Lee, et al.; Bull. Korean Chem. Soc. 28, 855 (2007) | (4) L. Xue, et al.; Inorg. Chem. 47, 4310 (2008) | (5) T. Sakamoto, et al.; Chem. Commun. 2009, 141 (2009) | (6) L. You, et al.; Nat. Chem. 3, 943 (2011) | (7) H.T. Ngo, et al.; Chem. Soc. Rev. 41, 4928 (2012)

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