Nickamine

CHF 115.00
In stock
CDX-B0150-M100100 mgCHF 115.00
CDX-B0150-M500500 mgCHF 459.00
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Product Details
Synonyms Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride; Chloro[N2-[2-(dimethylamino-κN)phenyl]-N1,N1-dimethyl-1,2-benzenediaminato-κN1,κN2]-nickel
Product Type Chemical
Properties
Formula C16H20ClN3Ni
MW 348.5
CAS 1033772-47-2
Source/Host Chemicals Synthetic
Purity Chemicals ≥97% (NMR)
Appearance Grey powder.
Solubility Soluble in DMSO, THF, 1,4-dioxane, chloroform, dichloromethane, DMA and toluene. Insoluble in alkanes and water.
Identity Determined by 1H-NMR.
Declaration Manufactured by Chemodex.
Other Product Data

Click here for Original Manufacturer Product Datasheet
Our product description may differ slightly from the original manufacturers product datasheet.

InChi Key IRLHVNUEEKJBEL-UHFFFAOYSA-M
Smiles C[N]1(C)C2=CC=CC=C2N2C3=C(C=CC=C3)[N](C)(C)[Ni]12Cl
Shipping and Handling
Shipping AMBIENT
Short Term Storage +4°C
Long Term Storage +4°C
Handling Advice Keep cool and dry.
Protect from light and moisture.
Use/Stability Stable for at least 2 years after receipt when stored at +4°C.
Documents
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Product Specification Sheet
Datasheet Download PDF

Reagent used as a catalyst for cross-coupling reactions between alkyl halides and carbon nucleophiles. Catalyst for alkyl-alkyl Kumada coupling of secondary alkyl halides, direct alkylation of heterocyclic C-H bonds, Sonogashira coupling of nonactivated alkyl halides, Kumada-Corriu-Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles. Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation.

Product References

(1) Z. Csok, et al.; JACS 130, 8156 (2008) | (2) O. Vechorkin, et al.; JACS 131, 9756 (2009) | (3) O. Vechorkin, et al.; JACS 131, 12078 (2009) | (4) O. Vechorkin & X. Hu; Angew. Chem. Inter. Ed. 48, 2937 (2009) | (5) O. Vechorkin, et al.; Angew. Chem. Inter. Ed. 49, 3061 (2010) | (6) P. Ren, et al.; JACS 133, 7084 (2011) | (7) X. Hu; Chimia 66, 154 (2012) | (8) J. Breitenfeld & X. Hu; Chimia 68, 235 (2014)

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