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Chemodex
Nickamine
122
CHF
CHF 122.00
In stock
CDX-B0150-M100100 mgCHF 122.00
CDX-B0150-M500500 mgCHF 489.00
| Product Details | |
|---|---|
| Synonyms | Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride; Chloro[N2-[2-(dimethylamino-κN)phenyl]-N1,N1-dimethyl-1,2-benzenediaminato-κN1,κN2]-nickel |
| Product Type | Chemical |
| Properties | |
| Formula |
C16H20ClN3Ni |
| MW | 348.5 |
| CAS | 1033772-47-2 |
| Source/Host Chemicals | Synthetic |
| Purity Chemicals | ≥95% (NMR) |
| Appearance | Grey powder. |
| Solubility | Soluble in DMSO, THF, 1,4-dioxane, chloroform, dichloromethane, DMA and toluene. Insoluble in alkanes and water. |
| Identity | Determined by 1H-NMR. |
| Declaration | Manufactured by Chemodex. |
| Other Product Data |
Click here for Original Manufacturer Product Datasheet |
| InChi Key | IRLHVNUEEKJBEL-UHFFFAOYSA-M |
| Smiles | C[N]1(C)C2=CC=CC=C2N2C3=C(C=CC=C3)[N](C)(C)[Ni]12Cl |
| Shipping and Handling | |
| Shipping | AMBIENT |
| Short Term Storage | +4°C |
| Long Term Storage | +4°C |
| Handling Advice |
Keep cool and dry. Protect from light and moisture. |
| Use/Stability | Stable for at least 2 years after receipt when stored at +4°C. |
| Documents | |
| MSDS |
 Download PDF |
| Product Specification Sheet | |
| Datasheet |
Download PDF |
Description
Reagent used as a catalyst for cross-coupling reactions between alkyl halides and carbon nucleophiles. Catalyst for alkyl-alkyl Kumada coupling of secondary alkyl halides, direct alkylation of heterocyclic C-H bonds, Sonogashira coupling of nonactivated alkyl halides, Kumada-Corriu-Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles. Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation.
Product References
(1) Z. Csok, et al.; JACS 130, 8156 (2008) | (2) O. Vechorkin, et al.; JACS 131, 9756 (2009) | (3) O. Vechorkin, et al.; JACS 131, 12078 (2009) | (4) O. Vechorkin & X. Hu; Angew. Chem. Inter. Ed. 48, 2937 (2009) | (5) O. Vechorkin, et al.; Angew. Chem. Inter. Ed. 49, 3061 (2010) | (6) P. Ren, et al.; JACS 133, 7084 (2011) | (7) X. Hu; Chimia 66, 154 (2012) | (8) J. Breitenfeld & X. Hu; Chimia 68, 235 (2014)
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