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Chemodex
cis-Bis-(isothiocyanato)-bis-(2,2'-bipyridyl- 4,4'-dicarboxylato)-ruthenium(II)
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Product Details | |
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Synonyms | N3 Foundation Dye; N3 Dye; Ruthenizer 535; cis-Bis(isothiocyanato)bis(2,2'-bipyridyl-4,4'-dicarboxylato)ruthenium(II) |
Product Type | Chemical |
Properties | |
Formula | C26H16N6O8RuS2 |
MW | 705.63 |
CAS | 141460-19-7 |
Source/Host Chemicals | Synthetic |
Purity Chemicals | ≥95% (NMR) |
Appearance | Dark-blue to black crystalline powder. |
Solubility | Soluble in DMF, methanol, ethanol or DMSO. |
Identity | Determined by 1H-NMR. |
Declaration | Manufactured by Chemodex. |
Other Product Data |
Click here for Original Manufacturer Product Datasheet |
InChi Key | VMISXESAJBVFNH-UHFFFAOYSA-N |
Smiles | S=C=N[Ru]12([N]3=CC=C(C(O)=O)C=C3C4=[N]1C=CC(C(O)=O)=C4)([N]5=CC=C(C(O)=O)C=C5C6=[N]2C=CC(C(O)=O)=C6)N=C=S |
Shipping and Handling | |
Shipping | AMBIENT |
Short Term Storage | +20°C |
Long Term Storage | +20°C |
Handling Advice |
Keep under inert gas. Very hygroscopic. |
Use/Stability | Stable for at least 2 years after receipt when stored at RT. |
Documents | |
Product Specification Sheet | |
Datasheet |
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Description
cis-Bis(isothiocyanato)bis(2,2'-bipyridyl-4,4'-dicarboxylato)ruthenium(II) is known to very efficiently photo-sensitize titanium dioxide (titania) in the visible spectrum up to a wavelength of ~750nm. This compound is commonly referred as N3 dye in the literature. It is so far one of the best pigments for Dye Solar Cells, and is considered an industry standard. The N3 dye can be coated on electrodes for improving the sensitivity of the dye sensitized solar cells (DSSCs) which can further enhance the power conversion efficiency (PCE). The N3 dye is used to prepare staining solutions in which metal-oxide semi-conductor electrodes will be immersed. The dye naturally adsorbs on the semi-conductor surface, resulting in a colored electrode bearing a sensitizing layer of dye molecules. N3 acts as a fluorescent sensitive luminescence turn-on type anion sensor in aqueous solution. Spectral Data: Absorption λmax: 538nm; 398nm; 314nm (ε/10^4 M-1cm-1). Emission λmax: 830nm (EtOH).
Product References
(1) M.K. Nazeeruddin, et al.; JACS 115, 6382 (1993) | (2) O. Kohle, et al.; Inorg. Chem. 35, 4779 (1996) | (3) O. Kohle, et al.; Adv. Mat. 9, 904 (1997) | (4) N. Kopidakis, et al.; J. Phys. Chem. B 107, 11307 (2003) | (5) F. Fabregat-Santiago, et al.; Sol. Energy Mat. Solar Cells, 87, 117 (2005) | (6) S.-H. Fan, et al; Inorg. Chim. Acta 362, 5155 (2009) | (7) S. Ardo, et al.; JACS 132, 6696 (2010) | (8) T. Nomoto, et al.; J. Chem. Phys. 138, 224704 (2013) | (9) A.A. Logunov, et al.; Semiconductors 48, 683 (2014) | (10) H.K. Wayment-Steele, et al.; CS Appl. Mater. Interfaces 6, 9093 (2014)