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cis-Bis-(isothiocyanato)-bis-(2,2'-bipyridyl- 4,4'-dicarboxylato)-ruthenium(II)

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Product Details
Synonyms N3 Foundation Dye; N3 Dye; Ruthenizer 535; cis-Bis(isothiocyanato)bis(2,2'-bipyridyl-4,4'-dicarboxylato)ruthenium(II)
Product Type Chemical
Properties
Formula C26H16N6O8RuS2
MW 705.63
CAS 141460-19-7
Source/Host Chemicals Synthetic
Purity Chemicals ≥95% (NMR)
Appearance Dark-blue to black crystalline powder.
Solubility Soluble in DMF, methanol, ethanol or DMSO.
Identity Determined by 1H-NMR.
Declaration Manufactured by Chemodex.
Other Product Data

Click here for Original Manufacturer Product Datasheet
Our product description may differ slightly from the original manufacturers product datasheet.

InChi Key VMISXESAJBVFNH-UHFFFAOYSA-N
Smiles S=C=N[Ru]12([N]3=CC=C(C(O)=O)C=C3C4=[N]1C=CC(C(O)=O)=C4)([N]5=CC=C(C(O)=O)C=C5C6=[N]2C=CC(C(O)=O)=C6)N=C=S
Shipping and Handling
Shipping AMBIENT
Short Term Storage +20°C
Long Term Storage +20°C
Handling Advice Keep under inert gas.
Very hygroscopic.
Use/Stability Stable for at least 2 years after receipt when stored at RT.
Documents
Product Specification Sheet
Datasheet Download PDF
Description
cis-Bis(isothiocyanato)bis(2,2'-bipyridyl-4,4'-dicarboxylato)ruthenium(II) is known to very efficiently photo-sensitize titanium dioxide (titania) in the visible spectrum up to a wavelength of ~750nm. This compound is commonly referred as N3 dye in the literature. It is so far one of the best pigments for Dye Solar Cells, and is considered an industry standard. The N3 dye can be coated on electrodes for improving the sensitivity of the dye sensitized solar cells (DSSCs) which can further enhance the power conversion efficiency (PCE). The N3 dye is used to prepare staining solutions in which metal-oxide semi-conductor electrodes will be immersed. The dye naturally adsorbs on the semi-conductor surface, resulting in a colored electrode bearing a sensitizing layer of dye molecules. N3 acts as a fluorescent sensitive luminescence turn-on type anion sensor in aqueous solution. Spectral Data: Absorption λmax: 538nm; 398nm; 314nm (ε/10^4 M-1cm-1). Emission λmax: 830nm (EtOH).
Product References
(1) M.K. Nazeeruddin, et al.; JACS 115, 6382 (1993) | (2) O. Kohle, et al.; Inorg. Chem. 35, 4779 (1996) | (3) O. Kohle, et al.; Adv. Mat. 9, 904 (1997) | (4) N. Kopidakis, et al.; J. Phys. Chem. B 107, 11307 (2003) | (5) F. Fabregat-Santiago, et al.; Sol. Energy Mat. Solar Cells, 87, 117 (2005) | (6) S.-H. Fan, et al; Inorg. Chim. Acta 362, 5155 (2009) | (7) S. Ardo, et al.; JACS 132, 6696 (2010) | (8) T. Nomoto, et al.; J. Chem. Phys. 138, 224704 (2013) | (9) A.A. Logunov, et al.; Semiconductors 48, 683 (2014) | (10) H.K. Wayment-Steele, et al.; CS Appl. Mater. Interfaces 6, 9093 (2014)
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