Chemodex

Selectofluor

Name: Selectofluor
Brand: Chemodex
SKU: CDX-S0356
Price: 103.00 CHF
Availability: InStock

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CDX-S0356-G02525 gCHF 103.00

CDX-S0356-G100100 gCHF 232.00

Specifications / Handling

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Product Details
Synonyms	1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate); F-TEDA-BF4
Product Type	Chemical
Properties
Formula	C₇H₁₄B₂ClF₉N₂
MW	354.26
CAS	140681-55-6
Source/Host Chemicals	Synthetic
Purity Chemicals	≥98%
Appearance	White to off-white powder.
Solubility	Soluble in water, DMSO, ethanol or DMF.
Identity	Determined by ¹H-NMR.
Declaration	Manufactured by Chemodex.
Other Product Data	Click here for Original Manufacturer Product Datasheet Our product description may differ slightly from the original manufacturers product datasheet.
InChi Key	REEJSGMVBVSCDW-UHFFFAOYSA-N
Smiles	ClC[N+]12CC[N+](CC2)(F)CC1.F[B-](F)(F)F.F[B-](F)(F)F
Shipping and Handling
Shipping	AMBIENT
Short Term Storage	+20°C
Long Term Storage	+4°C
Handling Advice	Protect from light and moisture.
Use/Stability	Stable for at least 2 years after receipt when stored at +4°C.
Documents
Product Specification Sheet
Datasheet	Download PDF

Scientific Background Information

Product Description

Selectfluor (F-TEDA-BF4) is a powerful, stable, and easy-to-handle electrophilic fluorinating reagent widely used in organic synthesis. It enables the direct introduction of fluorine into a broad range of substrates, including aromatics, heteroaromatics, alkenes, and activated C-H bonds, under mild conditions with high selectivity. Selectfluor also functions as a strong selective oxidizing agent and has applications in oxidative coupling, halogenation, and late-stage functionalization of complex molecules.

Product-specific References

(1) R.E. Banks; J. Chem. Soc. Chem. Commun. 1994, 343 (1994) | (2) G. Sankar Lal, et al.; J. Org. Chem. 60, 7340 (1995) | (3) R.E. Banks; J. Chem. Soc. Perkin Trans. 1, 2069 (1996) | (4) G. Sankar Lal, et al.; Chem. Rev. 96, 1737 (1996) | (5) R.E. Banks; J. Fluorine Chem. 87, 1 (1998) | (6) G. Stavber, et al.; Org. Lett. 6, 4973 (2004) | (7) P.T. Nyffeler, et al.; Angew. Chem. Int Ed. 44, 192 (2005) | (8) L. Manral; Synlett Spotlight 155, 807 (2006) | (9) G. Stavber; Molecules 26, 6432 (2011) | (10) T.C Allmann, et al.; Chemistry 22, 111 (2016) | (11) J.D. Galloway, et al.; Org. Lett. 19, 5772 (2017)

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