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Chemodex
Selectofluor
CHF 0.00
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| Product Details | |
|---|---|
| Synonyms | 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate); F-TEDA-BF4 |
| Product Type | Chemical |
| Properties | |
| Formula | C7H14B2ClF9N2 |
| MW | 354.26 |
| CAS | 140681-55-6 |
| Source/Host Chemicals | Synthetic |
| Purity Chemicals | ≥98% |
| Appearance | White to off-white powder. |
| Solubility | Soluble in water, DMSO, ethanol or DMF. |
| Identity | Determined by 1H-NMR. |
| Declaration | Manufactured by Chemodex. |
| Other Product Data |
Click here for Original Manufacturer Product Datasheet |
| InChi Key | REEJSGMVBVSCDW-UHFFFAOYSA-N |
| Smiles | ClC[N+]12CC[N+](CC2)(F)CC1.F[B-](F)(F)F.F[B-](F)(F)F |
| Shipping and Handling | |
| Shipping | AMBIENT |
| Short Term Storage | +20°C |
| Long Term Storage | +4°C |
| Handling Advice | Protect from light and moisture. |
| Use/Stability | Stable for at least 2 years after receipt when stored at +4°C. |
| Documents | |
| Product Specification Sheet | |
| Datasheet |
 Download PDF |
Description
Selectfluor (F-TEDA-BF4) is a powerful, stable, and easy-to-handle electrophilic fluorinating reagent widely used in organic synthesis. It enables the direct introduction of fluorine into a broad range of substrates, including aromatics, heteroaromatics, alkenes, and activated C-H bonds, under mild conditions with high selectivity. Selectfluor also functions as a strong selective oxidizing agent and has applications in oxidative coupling, halogenation, and late-stage functionalization of complex molecules.
Product References
(1) R.E. Banks; J. Chem. Soc. Chem. Commun. 1994, 343 (1994) | (2) G. Sankar Lal, et al.; J. Org. Chem. 60, 7340 (1995) | (3) R.E. Banks; J. Chem. Soc. Perkin Trans. 1, 2069 (1996) | (4) G. Sankar Lal, et al.; Chem. Rev. 96, 1737 (1996) | (5) R.E. Banks; J. Fluorine Chem. 87, 1 (1998) | (6) G. Stavber, et al.; Org. Lett. 6, 4973 (2004) | (7) P.T. Nyffeler, et al.; Angew. Chem. Int Ed. 44, 192 (2005) | (8) L. Manral; Synlett Spotlight 155, 807 (2006) | (9) G. Stavber; Molecules 26, 6432 (2011) | (10) T.C Allmann, et al.; Chemistry 22, 111 (2016) | (11) J.D. Galloway, et al.; Org. Lett. 19, 5772 (2017)