Chemodex

meso-Tetraphenyl-tetrabenzoporphine palladium complex

CHF 231.00
In stock
CDX-T0083-M02525 mgCHF 231.00
CDX-T0083-M250250 mgCHF 1'875.00
More Information
Product Details
Synonyms PdPh4TBP; PdTPBP
Product Type Chemical
Properties
Formula C60H36N4Pd
MW 919.392
CAS 119654-64-7
Source/Host Chemicals Synthetic.
Purity Chemicals ≥97% (NMR)
Appearance Deep blue powder.
Solubility Soluble in dichloromethane, toluene or acetonitrile.
Identity Determined by 1H-NMR.
Declaration Manufactured by Chemodex.
Other Product Data

Click here for Original Manufacturer Product Datasheet
Our product description may differ slightly from the original manufacturers product datasheet.

InChi Key WOKKIHAKMSHWEZ-XJTLWADGSA-N
Smiles C1=CC=C(C=C1)C1=C2C3=C(C=CC=C3)C3=[N]2[Pd++]24[N-]5C1=C1C=CC=CC1=C5C(=C1C5=C(C=CC=C5)C(C(=C5[N-]2C(C2=C5C=CC=C2)=C3C2=CC=CC=C2)C2=CC=CC=C2)=[N]41)C1=CC=CC=C1
Shipping and Handling
Shipping AMBIENT
Short Term Storage +4°C
Long Term Storage +4°C
Handling Advice Protect from light and moisture.
Use/Stability Stable for at least 2 years after receipt when stored at +4°C.
Documents
MSDS Download PDF
Product Specification Sheet
Datasheet Download PDF
Description

Phosphorescent probe for measuring oxygen in very low concentrations. Luminescent marker for oxygen and pH in biomedical imaging. Used as sensitizer in the process of photon up-conversion based on triplet–triplet annihilation (TTA). Used as agent for PDT, optical limiters and other types of nonlinear optical materials.

Product References

(1) S.A. Vinogradov & D.F. Wilson; J. Chem. Soc. Perkin Trans. 2, 103 (1995) | (2) S.A. Vinogradov & D.F. Wilson; Oxygen Transport to Tissue XVIll p597-603 (1997) | (3) J.E. Rogers, et al.; J. Phys. Chem. A. 107, 11331 (2003) | (4) S. Baluschev, et al.; New J. Physics 10; 013007 (2008) | (5) A.Y. Lebedev, et al.; J. Phys. Chem. A. 112, 7723 (2008) | (6) S.M. Borisov, et al.; Anal. Chem. 80, 9435 (2008) | (7) S. Schreml, et al.; Theranostics 4, 721 (2014) | (8) O.S. Kwon, et al.; ACS Nano 10, 1512 (2016)

Photochromic reaction by red light via triplet fusion upconversion: A. Tokunaga, et al.; J. Am. Chem. Soc. 141, 17744 (2019)

Triplet-triplet annihilation photon upconversion from diphenylhexatriene and ring-substituted derivatives in solution: T. Mizokuro, et al.;  Phys. Chem. Chem. Phys. ahead of print (2022)

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