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Chemodex
meso-Tetraphenyl-tetrabenzoporphine palladium complex
Product Details | |
---|---|
Synonyms | PdPh4TBP; PdTPBP |
Product Type | Chemical |
Properties | |
Formula | C60H36N4Pd |
MW | 919.392 |
CAS | 119654-64-7 |
Source/Host Chemicals | Synthetic. |
Purity Chemicals | ≥97% (NMR) |
Appearance | Deep blue powder. |
Solubility | Soluble in dichloromethane, toluene or acetonitrile. |
Identity | Determined by 1H-NMR. |
Declaration | Manufactured by Chemodex. |
Other Product Data |
Click here for Original Manufacturer Product Datasheet |
InChi Key | WOKKIHAKMSHWEZ-XJTLWADGSA-N |
Smiles | C1=CC=C(C=C1)C1=C2C3=C(C=CC=C3)C3=[N]2[Pd++]24[N-]5C1=C1C=CC=CC1=C5C(=C1C5=C(C=CC=C5)C(C(=C5[N-]2C(C2=C5C=CC=C2)=C3C2=CC=CC=C2)C2=CC=CC=C2)=[N]41)C1=CC=CC=C1 |
Shipping and Handling | |
Shipping | AMBIENT |
Short Term Storage | +4°C |
Long Term Storage | +4°C |
Handling Advice | Protect from light and moisture. |
Use/Stability | Stable for at least 2 years after receipt when stored at +4°C. |
Documents | |
MSDS | Download PDF |
Product Specification Sheet | |
Datasheet | Download PDF |
Phosphorescent probe for measuring oxygen in very low concentrations. Luminescent marker for oxygen and pH in biomedical imaging. Used as sensitizer in the process of photon up-conversion based on triplet–triplet annihilation (TTA). Used as agent for PDT, optical limiters and other types of nonlinear optical materials.
(1) S.A. Vinogradov & D.F. Wilson; J. Chem. Soc. Perkin Trans. 2, 103 (1995) | (2) S.A. Vinogradov & D.F. Wilson; Oxygen Transport to Tissue XVIll p597-603 (1997) | (3) J.E. Rogers, et al.; J. Phys. Chem. A. 107, 11331 (2003) | (4) S. Baluschev, et al.; New J. Physics 10; 013007 (2008) | (5) A.Y. Lebedev, et al.; J. Phys. Chem. A. 112, 7723 (2008) | (6) S.M. Borisov, et al.; Anal. Chem. 80, 9435 (2008) | (7) S. Schreml, et al.; Theranostics 4, 721 (2014) | (8) O.S. Kwon, et al.; ACS Nano 10, 1512 (2016)
Photochromic reaction by red light via triplet fusion upconversion: A. Tokunaga, et al.; J. Am. Chem. Soc. 141, 17744 (2019)
Triplet-triplet annihilation photon upconversion from diphenylhexatriene and ring-substituted derivatives in solution: T. Mizokuro, et al.; Phys. Chem. Chem. Phys. ahead of print (2022)