Chemodex

Tetrabutylammonium tribromide

CHF 180.00
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CDX-T0602-G100100 gCHF 180.00
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Product Details
Synonyms TBABr3; Tetrabutylammoniumbromide-perbromide; N,N,N,N-Tetrabutylammonium tribromide
Product Type Chemical
Properties
Formula C16H36Br3N
MW 482.18
CAS 38932-80-8
Source/Host Chemicals Synthetic
Purity Chemicals ≥98% (T)
Appearance Dark yellow to dark orange powder.
Solubility Soluble in acetonitrille, chloroform, THF, dioxane. Insoluble in water.
Identity Determined by 1H-NMR.
Declaration Manufactured by Chemodex.
Other Product Data

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InChi Key XXSLZJZUSYNITM-UHFFFAOYSA-N
Smiles Br[Br-]Br.CCCC[N+](CCCC)(CCCC)CCCC
Shipping and Handling
Shipping AMBIENT
Short Term Storage +20°C
Long Term Storage +20°C
Handling Advice Protect from light and moisture.
Use/Stability Stable for at least 2 years after receipt when stored at RT.
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Product Specification Sheet
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Description

Tetrabutylammonium tribromide (TBABr3) is used as a reagent in organic synthesis, particularly in organic and organometallic chemistry. It is a quaternary ammonium salt and is composed of a tetrabutylammonium cation (C16H36N+) and three bromide anions (Br-). TBABr3 is a powerful brominating agent, to introduce bromine (Br) atoms into organic molecules, and it is particularly useful for bromination reactions in cases where other brominating agents might not be suitable or effective. The tetrabutylammonium cation in TBABr3 serves as a phase-transfer catalyst, facilitating the transfer of the bromide ions into the organic phase of a reaction. This allows for the selective bromination of various organic substrates. TBABr3 is used in a variety of organic reactions, including the preparation of intermediates for pharmaceuticals, and in other applications where the introduction of bromine is required.

Product References

(1) R. Gopinath & B.K. Patel; Org. Lett. 2, 4177 (2000) | (2) S. Naik, et al.; Org. Biomol. Chem. 2, 1670 (2004) | (3) X. Lin, et al.; Synth. Commun. 36, 3153 (2006) | (4) A.T. Khan, et al.; Carbohydr. Res. 346, 673 (2011) | (5) S. Gao, et al.; J. Org. Chem. 83, 9250 (2018) | (6) M. Belal, et al.; Org. Biomol. Chem. 20, 2562 (2022)

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