Chemodex

Ru(bpy)2(phen-5-NH2)(PF6)2

CHF 193.00
In stock
CDX-B0671-M0055 mgCHF 193.00
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Product Details
Synonyms Bis-(2,2'-bipyridin)-(5-amino-phenanthrolin)ruthenium bis(hexafluorophosphat)
Product Type Chemical
Properties
Formula C32H25N7Ru . 2PF6
MW 898.59
CAS 84537-86-0
Source/Host Chemicals Synthetic
Purity Chemicals ≥95% (NMR)
Appearance Red to dark purple powder.
Solubility Soluble in DMSO.
Identity Determined by 1H-NMR.
Declaration Manufactured by Chemodex.
Other Product Data

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Our product description may differ slightly from the original manufacturers product datasheet.

InChi Key QQMMCXKCYXQNNA-UHFFFAOYSA-N
Smiles C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC2=CC(=C3C=CC=NC3=C2N=C1)N.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.[Ru+2] [F-][P+5]([F-])([F-])([F-])([F-])[F-].NC1=CC2=CC=C[N]3=C2C=4C1=CC=C[N]4[Ru+2]563([N]=7C=CC=CC7C=8C=CC=C[N]85)[N]=9C=CC=CC9C=%10C=CC=C[N]%106
Shipping and Handling
Shipping AMBIENT
Short Term Storage -20°C
Long Term Storage -20°C
Handling Advice Protect from light and moisture.
Use/Stability Stable for at least 2 years after receipt when stored at -20°C.
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Product Specification Sheet
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Description

Ru(bpy)2(phen-5-NH2)(PF6)2 is a fluorescent metal-ligand complex probe. It shows high brightness and large Stokes Shift. Spectral Data: λex=458nm; λem=612nm in 0.1 M Tris pH 7.0. It has been used as starting material for synthesis of long-lifetime luminescent Ru complexes and in the preparation of amino-ruthenium(ii) complex functionalized gold nanoparticles, which could be used as probe in biosensors and bioassays. Ru(bpy)2(phen-5-NH2)(PF6)2 is has also been used to synthesize fluorescent silica nanoparticles with ultrabrightness and photostability by encapsulating it into silica nanoparticles by a modified reversed microemulsion method. Could be used for the determination of nucleotide base sequences.

Product References

(1) C.D. Ellis, et at.; Inorg. Chem. 22, 1283 (1983) | (2) E. Terpetschnig, et al.; Anal. Biochem. 251, 241 (1997) | (3) F.N. Castellano et al.; Anal. Bioch. 255, 165 (1998) | (4) J.H. Snook, et al.; Org. Electron. 6, 55 (2005) | (5) J. Weh, et al.; ChemBioChem 8, 122 (2007) | (6) Y. Yu, et al.; J. Mat. Chem. 21, 12622 (2011) | (7) E. de la Llave, et al.; J. Phys. Chem. C 118, 21420 (2014) | (8) D. Lu, et al.; RSC Adv. 6, 51597 (2016) | (9) T. Wang, et al.; Anal. Chim. Acta 1062, 124 (2019) | (10) D. Bahari, et al.; Anal. Chim. Acta 1132, 55 (2020)

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