Chemodex

Diphenyliodonium triflate

CHF 264.00
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CDX-D0091-G0055 gCHF 264.00
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Product Details
Synonyms DPIT; Diphenyliodonium trifluoromethanesulfonate
Product Type Chemical
Properties
Formula C13H10F3IO3S
MW 430.18
CAS 66003-76-7
Source/Host Chemicals Synthetic
Purity Chemicals ≥98% (NMR)
Appearance Light yellow crystalline.
Solubility Soluble in acetone, chloroform, DMF or DMSO.
Identity Determined by 1H-NMR.
Declaration Manufactured by Chemodex.
Other Product Data

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Our product description may differ slightly from the original manufacturers product datasheet.

InChi Key SBQIJPBUMNWUKN-UHFFFAOYSA-M
Smiles [O-]S(=O)(C(F)(F)F)=O.C1([I+]C2=CC=CC=C2)=CC=CC=C1
Shipping and Handling
Shipping AMBIENT
Short Term Storage +20°C
Long Term Storage +20°C
Handling Advice Protect from light and moisture.
Use/Stability Stable for at least 2 years after receipt when stored at RT.
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Product Specification Sheet
Datasheet Download PDF
Description

Reagent for synthesis. Used for α-phenylation of cyclic ketones, N-, O-, P-, and S-phenylation reactions. Phenylating agent for palladium-catalyzed cross-couplings, click chemistry and photochemistry.

Product References

(1) J.L. Dektar & N.P.; J. Org. Chem. 55, 639 (1990) | (2) J.H. Ryan & P.J. Stang; Tetrahed. Lett. 38, 5061 (1997) | (3) S.A. Jacobsen, et al.; J. Chem. Soc. Perkin Trans. I 1999, 3265 (1999) | (4) U. Radhakrishnan & P.J. Stang; Org. Lett. 3, 859 (2001) | (5) V.K. Aggarwal & B. Olofsson; Angew. Chem. Int. Ed. 44, 5516 (2005) | (6) J.-M. Becht & C. Drian; Org. Lett. 10, 3161 (2008) | (7) J. Aydin, et al.; Org. Lett. 11, 2852 (2009) | (8) D. Kumar & V.B. Reddy; Synthesis 10, 1687 (2010) | (9) D. Lapointe, et al.; Org. Chem. 76, 749 (2011) | (10) J.-M. Becht; Encycl. Reag. Org. Synth. (2011)

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