Chemodex

Dichlorobis(2,2'-bipyridine)ruthenium(II)

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Synonyms Ru(bpy)2Cl2; (bpy)2RuCl2; λ²-ruthenium(2+) bis(2,2'-bipyridine) dichloride; Bis(2,2′-bipyridine)dichlororuthenium(II); NSC 296660
Product Type Chemical
Properties
Formula C20H16Cl2N4Ru
MW 484.34
CAS 15746-57-3
Source/Host Chemicals Synthetic
Purity Chemicals ≥85% (HPLC)
Appearance Solid.
Solubility Soluble in water or methanol.
Identity Determined by 1H-NMR.
Declaration Manufactured by Chemodex.
Other Product Data

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InChi Key MGAJEYXQYJBLQL-UHFFFAOYSA-L
Smiles Cl[Ru]12([N]3=CC=CC=C3C4=[N]2C=CC=C4)(Cl)[N]5=CC=CC=C5C6=[N]1C=CC=C6
Shipping and Handling
Shipping AMBIENT
Short Term Storage +4°C
Long Term Storage -20°C
Handling Advice Keep under inert gas.
Protect from light and oxygen.
Use/Stability Stable for at least 2 years after receipt when stored at -20°C.
Documents
Product Specification Sheet
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Description
Dichlorobis(2,2'-bipyridine)ruthenium(II) (Ru(bpy)2Cl2) is a coordination complex widely used as a versatile building block in inorganic and materials chemistry. Featuring a ruthenium(II) center bound to two 2,2'-bipyridine ligands and two chloride ions, it serves as a key precursor for the synthesis of polypyridyl ruthenium derivatives. The compound is valued in photochemistry and electrochemistry for its tunable redox properties and strong visible-light absorption, making it useful in studies of electron transfer, catalysis, dye-sensitized solar cells, and luminescent probes. Spectral: Absorption ~456nm.
Product References
(1) B.P. Sullivan, et al.; Inorg. Chem. 17, 3334 (1978) | (2) A. Basu, et al.; Inorg. Chem. 21, 2231 (1982) | (3) A.Z. Genack, et al.; Anal. Chem. 56, 2957 (1984) | (4) T.C. Strekas & S.K. Mandal; J. Raman Spectr. 15, 109 (1984) | (5) D.S. Eggleszon, et al.; Inorg. Chem. 24, 4573 (1985) | (6) P.A. Lay, et al.; Inorg. Synth. 24, 291 (1986) | (7) C.R. Leidner, et al.; Inorg. Chem. 26, 882 (1987) | (8) G. Giuffrida, et al.; Chem. Phys. Lett. 180, 28 (1991) | (9) Y. Liu, et al.; Chem. Commun. 2005, 1702 (2005) | (10) O.S. Odongo, et al.; Inorg. Chem. 47, 7493 (2008) | (11) K. Neuthe, et al.; Dyes Pigm. 104, 24 (2014) | (12) A.S. Abel, et al.; Chemosensors 10, 79 (2022)
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