Chemodex

(1R)-(-)-Nopol

Name: (1R)-(-)-Nopol
Brand: Chemodex
SKU: CDX-N0658
Price: 58.00 CHF
Availability: InStock

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CDX-N0658-G05050 gCHF 58.00

CDX-N0658-G100100 gCHF 90.00

Specifications / Handling

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Product Details
Synonyms	(1R)-Nopol; (-)-Nopol; NSC1284; 6,6-Dimethyl-2-norpinen-2-ethanol; (1R)-6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol
Product Type	Chemical
Properties
Formula	C₁₁H₁₈O
MW	166.26
CAS	35836-73-8
RTECS	RC8870000
Source/Host Chemicals	Synthetic
Purity Chemicals	≥98% (GC)
Appearance	Colourless viscous liquid.
Solubility	Slightly soluble in chloroform or MeOH.
Identity	Determined by ¹H-NMR.
Declaration	Manufactured by Chemodex.
Other Product Data	Click here for Original Manufacturer Product Datasheet Our product description may differ slightly from the original manufacturers product datasheet.
InChi Key	ROKSAUSPJGWCSM-UWVGGRQHSA-N
Smiles	OCCC1=CC[C@]2([H])C(C)(C)[C@@]1([H])C2
Shipping and Handling
Shipping	AMBIENT
Short Term Storage	+20°C
Long Term Storage	+20°C
Handling Advice	Protect from light and moisture.
Use/Stability	Stable for at least 2 years after receipt when stored at RT.
Documents
Product Specification Sheet
Datasheet	Download PDF

Scientific Background Information

Product Description

(1R)-Nopol is a chiral terpenol derivative, that can be used as a building block and intermediate for synthesis. Has been used in the preparation of optically active O,O-diterpenyl dithiophosphoric and O-terpenyl aryldithiophosphonic acids. Reacts with silver hexafluoroantimonate to form a complex, which can be an effective initiator for the nonthermal curing of epoxy resins by electron beam induced cationic polymerization. Can be used as a starting material for Pinaverium bromide, a selective gastrointestinal calcium ion antagonist used to treat irritable bowel syndrome. Due to its woody and minty aroma, Nopol is often used as a starting material for flavorings and fragrances. Gives a clean note for soaps and detergents.

Product-specific References

(1) D.R. Arnold & X. Du; Can. J. Chem. 72, 403 (1994) | (2) M. Miyazawa, et al.; Phytochem. 39, 337 (1995) | (3) J.V. Crivello & S.S. Liu; J. Polymer Sci. Part A Polymer Chem. 37, 1199 (1999) | (4) L. Cointeaux, et al.; Tetrahedr. Lett. 43, 6275 (2002) | (5) E. Barriau, et al.; Macromolecules 41, 3779 (2008) | (6) R.A. Cherkasov, et al.; Phosph. Sulfur Relat. Elem. 186, 1003 (2011)

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