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Chemodex
Tetrahexylammonium hydrogensulfate
Product Details | |
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Synonyms | Tetra-n-Hexylammonium hydrogen sulfate; THAHS |
Product Type | Chemical |
Properties | |
Formula | C24H53NO4S |
MW | 451.75 |
CAS | 32503-34-7 |
Source/Host Chemicals | Synthetic |
Purity Chemicals | ≥98% (Titr.) |
Appearance | Colorless or white powder or crystals. |
Solubility | Soluble in methanol or DMSO. |
Identity | Determined by 1H-NMR. |
Declaration | Manufactured by Chemodex. |
Other Product Data |
Click here for Original Manufacturer Product Datasheet |
InChi Key | RULHPTADXJPDSN-UHFFFAOYSA-M |
Smiles | OS([O-])(=O)=O.CCCCCC[N+](CCCCCC)(CCCCCC)CCCCCC |
Shipping and Handling | |
Shipping | AMBIENT |
Short Term Storage | +20°C |
Long Term Storage | +20°C |
Handling Advice |
Keep under inert gas. Very hygroscopic. |
Use/Stability | Stable for at least 2 years after receipt when stored at RT. |
Documents | |
MSDS | Inquire |
Product Specification Sheet | |
Datasheet | Download PDF |
Tetrahexylammonium hydrogensulfate (THAHS) is a quaternary ammonium salt used in various chemical and biochemical applications. It consists of a tetracationic ammonium ion (C6H13)4N+ and a hydrogen sulfate anion (HSO4-). THAHS is used as a phase-transfer catalyst (PCT) and can facilitate various chemical reactions by aiding in the transfer of reactants between immiscible phases. Phase-transfer catalysis involves the transfer of reactants from one phase (usually an aqueous phase) to another phase (usually an organic phase) to facilitate a chemical reaction. THAHS can be employed in organic synthesis, particularly in reactions that involve the transfer of anions or reagents between organic and aqueous phases. Some common applications include, quaternization reactions, nucleophilic substitution reactions or halogenation reactions. It can also be used in processes that involve the extraction or separation of specific ions or compounds from one phase to another.
(1) R. Bar, et al.; J. Mol. Catal. 16, 175 (1982) | (2) D. Feldmann & M. Rabinovitz; J. Org. Chem. 53, 3779 (1988) | (3) L.G Sayers, et al.; Biochem. Soc. Trans. 21, 105S (1993) | (4) T.S. Straub; Tetrahedr. Lett. 36, 663 (1995) | (5) S. Amaratunga & H. Alper; J. Organometall. Chem. 488, 25 (1995) | (6) L.J. Csanyi & K. Jaky; Phys. Chem. Chem. Phys. 3, 2018 (2001) | (7) R.J. Fox & J. Qiu; Org. Process Res. Dev. 24, 235 (2020)